Studies on the Mechanism of the Alkaline Hydrolysis
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چکیده
Title STUDIES ON THE MECHANISM OF THE ALKALINE HYDROLYSIS OF THIOLSULFINATES Redacted for Privacy Abstract approved (Major professor) The alkaline hydrolysis of phenylbenzenethiolsulfinate was studied at various pHs in an aqueous solution of 25% dioxane. A pH stat was constructed to follow the rate of disappearance of hydroxide ion under pseudofirst -order conditions. Comparative studies were made under identical conditions by following the disappearance of the thiolsulfinate in a buffered solution in the ultraviolet at 296 m,t(. A product study was made which indicates that the reaction follows the course indicated in Equation 1.
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تاریخ انتشار 2014